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2004
Thioethers
Q 0580
50- 056
Studies on the Regio- and Stereoselectivity of Halohydroxylation of 1,2-Allenyl
Sulfides or Selenides. — Based on the previously reported iodohydroxylation of
1,2-allenyl sulfides, the corresponding bromohydroxylation of 1,2-allenyl sulfides, and
iodohydroxylation of 1,2-allenyl selenides is studied. In all cases, a fairly good regioselectivity and good (Z)-selectivity is observed. The attempted bromohydroxylation of
1,2-allenyl selenides fails to yield the expected products. — (MA*, S.; HAO, X.;
MENG, X.; HUANG, X.; J. Org. Chem. 69 (2004) 17, 5720-5724; Dep. Chem.,
Zhejiang Univ., Hangzhou 310027, Peop. Rep. China; Eng.) — Klein
2004
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