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2004
Fused pyridine derivatives
R 0450
Approach to Geminally Alkylated Azaphthalans via a Consecutive Double DesiReaction: Application to a Synthesis of Cerpegin. — Two
50- 116 lylation—Alkylation
alkyl groups are introduced on the same α-carbon of azaphthalans in one pot by a consecutive double desilylationalkylation reaction. The product (IIIa) is used for the synthesis of (V) as a known precursor for the natural product cerpegin (VI). —
(SARKAR*, T. K.; BASAK, S.; Org. Lett. 6 (2004) 17, 2925-2927; Dep. Chem.,
Indian Inst. Technol., Kharagpur 721 302, India; Eng.) — Steudel
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