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2004
Terpenes
U 0200
50- 148
Synthesis of α-Hydroxy Ketones from Terpene Aldehydes. — Unsymmetrically
substituted α-hydroxy ketones such as (V) and (VII) possessing isoprenoid units are
synthesized from commercially available terpene aldehydes. Tautomerization of these
novel acyloins doesn't occur under the reaction conditions described but is observed
upon heating. Diastereomeric ketones are resolved via their camphanate esters. —
(SCHUELER, M.; ZORN, H.; SLAWIN, A. M. Z.; BERGER*, R. G.; Synth.
Commun. 34 (2004) 14, 2591-2600; Inst. Food Chem., Univ. Hannover,
D-30453 Hannover, Germany; Eng.) — R. Langenstrassen
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