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2004
Carbohydrates
U 0500
A Practical Method for the Stereoselective Generation of β-2-Deoxy Glycosyl
— The α-glycosyl chlorides are easily transformed to the corresponding
50- 166 Phosphates.
phosphates as a mixture of α- and β-derivatives. The latter, obtained on a large scale,
are converted to the corresponding TDP-derivatives and then separated, thus offering
a practical chemical method for obtaining the β-anomers of TDP 2-deoxy sugar donors
stereoselectively. — (OBERTHUER, M.; LEIMKUHLER, C.; KAHNE*, D.; Org.
Lett. 6 (2004) 17, 2873-2876; Dep. Chem., Princeton Univ., Princeton, NJ 08544,
USA; Eng.) — Steudel
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