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2004
Lipids
U 0750
50- 179
Sphingolipid Synthesis via Olefin Cross Metathesis: Preparation of a Differentially Protected Building Block and Application to the Synthesis of D-erythro-Ceramide. — The various building blocks are synthesized through the (E)-selective olefin
cross metathesis reaction of (IV). The attempts to use (I) as a precursor result in a very
poor performance. The utility of (VII) for the synthesis of (VIII) is demonstrated. —
(RAI, A. N.; BASU*, A.; Org. Lett. 6 (2004) 17, 2861-2863; Dep. Chem., Brown
Univ., Providence, RI 02912, USA; Eng.) — Steudel
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