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2004
Protection
O 0345
51- 054
One-Step C=N, C=O Bonds Cleavage and C=O, C=N Bonds Formation over Supported Ionic Liquid in Water. — A silica-supported ionic liquid is described as catalyst for the conversion of oximes (I) to carbonyl compounds (II) using acetone as the
scavenger. The transformation can be reversed using acetone oxime and carbonyl compounds (III) under similar conditions resulting in an efficient formation of oximes (IV).
— (LI, D.; SHI, F.; DENG*, Y.; Tetrahedron Lett. 45 (2004) 36, 6791-6794; Cent.
Green Chem. Catal., Lanzhou Inst. Chem. Phys., Chin. Acad. Sci., Lanzhou 730000,
Peop. Rep. China; Eng.) — Mais
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