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2004
Fused pyrrole derivatives
R 0160
Palladium-Catalyzed Cyclization/Carboalkoxylation of Alkenyl Indoles. — A
palladium-catalyzed cyclization/carboalkoxylation of alkenylindoles is reported.
51- 093 mild
Unprotected, electron-rich and electron-poor alkenylindoles undergo this cyclization/
carboalkoxylation affording the corresponding fused indoles in good yields and excellent regioselectivity, and, in the case of indoles that possess terminal olefinic substitution like (VIII), (IX) and (X) with high diastereoselectivity also. — (LIU, C.;
WIDENHOEFER*, R. A.; J. Am. Chem. Soc. 126 (2004) 33, 10250-10251; P.M.
Gross Chem. Lab., Duke Univ., Durham, NC 27708, USA; Eng.) — Bartels
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