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2004
Organo-phosphorus compounds
S 0080
C-Phosphorylated N-(Trichloroethylidene)sulfonamides: A New Type of Highly
Imines. — Imines of type (II) are prepared by a simple and convenient
51- 146 Electrophilic
approach, involving the dehydrogenation of phosphonates (I) by treatment with a pyridine—chlorine adduct as key step. The versatility of this new class of N-sulfonylimines
is demonstrated by N-phosphorylation, and nucleophilic addition of methanol and
thiols. — (RASSUKANA, Y. V.; ONYS'KO*, P. P.; DAVYDOVA, K. O.; SINITSA, A.
D.; Eur. J. Org. Chem. 2004, 17, 3643-3649; Inst. Org. Chem., Acad. Sci. Ukr., Kiev
253660, Ukraine; Eng.) — Klein
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