close

Вход

Забыли?

вход по аккаунту

?

код для вставки
2004
Iron
I 7100
52- 021
The First All-Cyanide Fe4S4 Cluster: [Fe4S4(CN)4]3-. — As revealed by single
crystal XRD, the compound (II) crystallizes in the rhombohedral space group R3c with
Z = 6. The [Fe4S4(CN)4]3- cluster anion resembles the protein Fe4 S+4 active sites geometrically, electrochemically, and spectroscopically. Cyclic voltammetry indicates that
(II) has the least negative [Fe4S4L4]2-/3- and [Fe4S4L4]3-/4- redox potentials (-0.4 and
-1.38V vs. Ag/AgCl, resp.) among all known synthetic analogues of the protein Fe4 S+4
active sites. — (SCOTT, T. A.; ZHOU*, H.-C.; Angew. Chem., Int. Ed. 43 (2004) 42,
5628-5631; Dep. Chem. Biochem., Miami Univ., Oxford, OH 45056, USA; Eng.) —
W. Pewestorf
Документ
Категория
Без категории
Просмотров
0
Размер файла
14 Кб
Теги
1/--страниц
Пожаловаться на содержимое документа