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2004
Enantioselective syntheses
O 0031
Enantioselective Hydrogenation of α-Aryloxy α,β-Unsaturated Acids. AsymmetSynthesis of α-Aryloxycarboxylic Acids. — The title reaction provides optically
52- 026 ric
active α-aryloxy acids and is catalyzed by a variety of (bisphosphine)ruthenium catalysts. RuCl2((S)-BINAP) is chosen as the best one. The method tolerates a variety of
substitution patterns on the aromatic ring as well as limited variation in substitution on
the olefin. — (MALIGRES*, P. E.; KRSKA, S. W.; HUMPHREY, G. R.; Org. Lett. 6
(2004) 18, 3147-3150; Dep. Process Res., Merck Res. Lab., Merck&Co., Inc.,
Rahway, NJ 07065, USA; Eng.) — Steudel
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