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2004
Technology of materials
V 1500
Thermodynamically Controlled Self-Assembly of Two-Dimensional Oxide Nanos— The spontaneous formation and subsequent aggregation of planar V6O12
52- 204 tructures.
clusters on a Rh(111) surface after deposition of V atoms at submonolayer coverages
under appropriate temperature and sufficiently oxidizing conditions is monitored by
STM. The stoichiometry and the geometry of the obtained starlike structures are characterized by ab initio DFT calculations. The fabrication of ultrathin layers of vanadium
oxides has potential commercial interest in monolayer catalysts, in advanced coating
systems, and in optical devices. — (SCHOISWOHL, J.; SURNEV, S.; SOCK, M.;
RAMSEY, M. G.; KRESSE, G.; NETZER*, F. P.; Angew. Chem., Int. Ed. 43 (2004)
41, 5546-5549; Inst. Experimentalphys., Karl-Franzens-Univ., A-8010 Graz, Austria;
Eng.) — W. Pewestorf
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