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2005
Amination
O 0268
01- 047
Scope and Utility of CsOH·H2O in Amination Reactions via Direct Coupling of
Aryl Halides and sec-Alicyclic Amines. — The use of CsOH·H2O in coupling of aryl
halides and sec-alicyclic amines allows rapid, efficient, and environmentally friendly
access to aryl substituted amines. A number of aryl halides and sec-alicyclic amines
can react successfully under these conditions. Chlorobenzene and fluorobenzene as
well as aryl halides containing p-hydroxy, p-formyl, or p-methoxy substituents do not
undergo amination. — (VARALA, R.; RAMU, E.; ALAM, M. M.; ADAPA*, S. R.;
Synlett 2004, 10, 1747-1750; Inorg. Chem. Div., Indian Inst. Chem. Technol.,
Hyderabad 500 007, India; Eng.) — Jannicke
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