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2005
Metathesis reactions
O 0286
Regioselective Cross-Metathesis Reaction Induced by Steric Hindrance. —
title reactions are observed with protected hexa-1,5-dien-3-ols when they are pro01- 051 The
tected by sterically hindered silyl groups. Good stereoselectivity is observed with electron-deficient olefins, and poor stereoselectivity is obtained with olefins having polar
functionalized groups at the β-position. — (BOUZBOUZ*, S.; SIMMONS, R.;
COSSY, J.; Org. Lett. 6 (2004) 20, 3465-3467; Lab. Chim. Org., CNRS, Ec. Super.
Phys. Chim. Ind., F-75231 Paris, Fr.; Eng.) — Steudel
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