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2005
Organo-silicon compounds
S 0060
Preparation of (Phenyldifluoromethyl)- and (Phenoxydifluoromethyl)-silanes by
Carbon-Chlorine Bond Activation. — The title silanes (III)
01- 145 Magnesium-Promoted
and (XIII) can easily be prepared by Mg-mediated treatment of the chlorides (I) and
(XII) with Tms-Cl. They smoothly react with various electrophiles to afford fluoro
compounds which are interesting building blocks. — (GUIDOTTI, J.; METZ, F.;
TORDEUX, M.; WAKSELMAN*, C.; Synlett 2004, 10, 1759-1762; SIRCOB,
CNRS, Univ. Versailles, F-78035 Versailles, Fr.; Eng.) — Jannicke
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