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2005
Amino acids
U 0400
Asymmetric Alkylation of Glycine Imine Esters Using Solid Supports Preloaded
Base. — Based on recent investigations, the factors affecting the enantioselectiv01- 164 with
ity and the rate of the title reaction are determined. Optimized conditions for the alkylation of Schiff base (III) are applied to the reaction with alkyl halides. In the presence of
residual water on the support, the reactions are dramatically accelerated to be complete
within a few minutes. — (YU, H.; TAKIGAWA, S.; KOSHIMA*, H.; Tetrahedron 60
(2004) 38, 8405-8410; Dep. Appl. Chem., Fac. Eng., Ehime Univ., Matsuyama, Ehime
790, Japan; Eng.) — Klein
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