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2005
Other bioactive products
U 1300
Stereodivergent Construction of Cyclic Ethers by a Regioselective and EnantioRhodium-Catalyzed Allylic Etherification: Total Synthesis of Gaur Acid.
01- 201 specific
— Stereospecific rhodium-catalyzed allylic etherification with secondary alkenyl alcohols in conjunction with ring-closing metathesis provides a direct approach to cis- and
trans-disubstituted cyclic ethers. The present new method can also be applied in the total synthesis of gaur acid (VIII). — (EVANS*, P. A.; LEAHY, D. K.; ANDREWS, W.
J.; URAGUCHI, D.; Angew. Chem., Int. Ed. 43 (2004) 36, 4788-4791; Dep. Chem.,
Indiana Univ., Bloomington, IN 47405, USA; Eng.) — S. Adam
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