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2005
Catalysts
H 2000
02- 019
Water Reduction and Oxidation on Pt—Ru/Y2Ta2O5N2 Catalyst under Visible
Light Irradiation. — Y2Ta2O5N2, prepared by nitriding YTaO4 powder under a flow
of NH3 at 1123 K, is a novel visible light driven photocatalyst with high activity for
oxidation of water in the presence of a sacrificial electron acceptor (Ag+). This catalyst
also reduces water to H2 in the presence of a sacrificial electron donor (ethanol) and Pt
or Ru as a co-catalyst, with significant enhancement of H2 production efficiency in the
presence of both Pt and Ru. — (DOMEN*, K.; et al.; Chem. Commun. (Cambridge)
2004, 19, 2192-2193; Chem. Resour. Lab., Tokyo Inst. Technol., Yokohama 226,
Japan; Eng.) — W. Pewestorf
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