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2005
Uranium
I 5900
02- 022
Synthesis and Characterization of Heavier Dioxouranium(VI) Dihalides. —
The structures of compounds (II) and (III) as well as of UO2Br2·3H2O (IV) and
[UO2Br2(OH2)2]2 (V) (prepared according to the literature) are determined by single
crystal XRD. Compounds (IV) and (V) crystallize in the monoclinic space group
P21/c with Z = 4 and Z = 2, respectively. The compounds (IIa) and (IIb) crystallize in
the tetragonal space group P21212 with Z = 4 and (III) is monoclinic, space group
P21/c, Z = 2. — (CRAWFORD*, M.-J.; ELLERN, A.; KARAGHIOSOFF, K.;
MAYER, P.; NOETH, H.; SUTER, M.; Inorg. Chem. 43 (2004) 22, 7120-7126; Inst.
Biochem., Ludwig-Maximilians-Univ., D-81377 Muenchen, Germany; Eng.) —
Schramke
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