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2005
Radical reactions
O 0195
A New, Practical Access to Amidyl Radicals. — Amidyl radicals are readily generfrom N-allylsulfonimides by the action of a xanthate and a small amount of a per02- 038 ated
oxide as initiator. The process involves extrusion of sulfur dioxide from an N-amidosulfonyl radical by rupture of the nitrogen-sulfur bond. In some cases, the N-amidosulfonyl radical is prematurely captured by the internal olefinic trap. — (MOUTRILLE*,
C.; ZARD, S. Z.; Chem. Commun. (Cambridge) 2004, 16, 1848-1849; Lab. Synth.
Org., CNRS, DCSO, Ec. Polytech., F-91128 Palaiseau, Fr.; Eng.) — M. Paetzel
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