close

Вход

Забыли?

вход по аккаунту

?

код для вставки
2005
Oxidation
O 0212
02- 039
Synthesis of Peroxide Compounds by the BF3-Catalyzed Reaction of Acetals and
Enol Ethers with H2O2. — The oxidation of aliphatic and alicyclic enol ethers
[cf. (IV)] and acetals [cf. (I)] proceeds smoothly with hydrogen peroxide in the presence of substoichiometric amounts of BF3·OEt2 to provide a new access to aliphatic and
alicyclic gem-bis-hydroperoxides (II) and (VI). Several secondary products like
endocyclic peroxides [cf. (VIII)] or bridged peroxides [cf. (III)] are obtained depending
on the reaction conditions applied. — (TERENT'EV, A. O.; KUTKIN, A. V.;
PLATONOV, M. M.; VORONTSOV, I. I.; ANTIPIN, M. Y.; OGIBIN*, Y. N.;
NIKISHIN, G. I.; Russ. Chem. Bull. 53 (2004) 3, 681-687; Zelinsky Inst. Org. Chem.,
Russ. Acad. Sci., Moscow 117913, Russia; Eng.) — Mischke
Документ
Категория
Без категории
Просмотров
0
Размер файла
197 Кб
Теги
1/--страниц
Пожаловаться на содержимое документа