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2005
Furan derivatives
R 0060
Enantioselective Synthesis of Functionalized γ-Butyrolactones. — Asymmetric
dihydroxylation and aminohydroxylation of 2-alkylidene glutarates offers an effective
02- 096 approach
to chiral butyrolactones. Interestingly, aminohydroxylation with the amine
(VIII) provides considerable amounts of the amino ester (X) which is an useful building
block of substituted piperidines. Dihydroxylation of the adipate (XIII) gives the diol
(XIV), a lactone is not obtained. — (SAMARAT, A.; AMRI*, H.; LANDAIS, Y.;
Tetrahedron 60 (2004) 40, 8949-8956; Lab. Chim. Org. Organomet., Fac. Sci.,
Campus Univ., 1060 Tunis, Tunisia; Eng.) — Jannicke
2005
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