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2005
Quinoline derivatives
R 0410
Synthesis and Fluorescence Properties of 3-Benzoxa- and Thiazol-2-ylquinoline-5
or 7-maleimides. — Four new amino-hetarylquinolines (IV)/(V) and their correspond02- 140 ing
maleimido derivatives (VIII) and (IX), resp., are synthesized and evaluated for their
emission properties and suitability as fluoroprobes. Compound (VIIIb) shows very
good enhancement in fluorescence upon thiol addition and thus can serve as a sensitive
thiol detection and quantitation reagent. Compound (Xa) forms a fluorescent conjugate
with the model proteine BSA and appears to be useful as a protein label that gives highly fluorescent protein bioconjugates. — (NAIR, J. S.; RAJASEKHARAN*, K. N.;
Indian J. Chem., Sect. B: Org. Chem. Incl. Med. Chem. 43 (2004) 9, 1944-1949;
Dep. Chem., Univ. Kerala, Trivandrum 695 034, Kerala, India; Eng.) — H. Toeppel
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