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2005
Theory of the condensed state
D 1000
Simulation of the Crystal Field Effect on the Pr3+ Ion in K2La1-xPrxCl5 Ternary
Chlorides. — Single crystals of the title compounds (0.02 ≤ x ≤ 0.15) are characterized
03- 004 by high resolution absorption, luminescence, and excitation spectroscopy at 4, 77, and
293 K. The samples crystallize in the orthorhombic space group Pnma with Z = 4. The
experimental 4f2 energy level scheme of the Pr3+ ion in K2LaCl5 is simulated by using
a phenomenological crystal field model yielding a satisfactory rms deviation of 17 cm-1
between the experimental and calculated energy level schemes. — (CYBINSKA, J.;
HOELSAE*, J.; LASTUSAARI, M.; LEGENDZIEWICZ, J.; MEYER, G.;
WICKLEDER, C.; J. Alloys Compd. 380 (2004) 1-2, 27-33; Dep. Chem., Univ.
Turku, SF-20014 Turku, Finland; Eng.) — W. Pewestorf
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