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2005
Addition reactions
O 0060
N-Allyl-N-tert-butyldimethylsilylamine for Chiral Ligand-Controlled AsymmetConjugate Addition to tert-Butyl Alkenoates. — The chiral controlled asym03- 041 ric
metric conjugate addition reaction of title compound (II) to alkenoates (I) proceeds with
high enantioselectivities. After protodesilylation the corresponding 3-allylaminoalkanoates (III) are obtained in high yields. The allyl group on the nitrogen atom is easily
removable by treatment with Wilkinson's catalyst. — (DOI, H.; SAKAI, T.;
YAMADA, K.-I.; TOMIOKA*, K.; Chem. Commun. (Cambridge) 2004, 16,
1850-1851; Grad. Sch. Pharm. Sci., Kyoto Univ., Sakyo, Kyoto 606, Japan; Eng.) —
M. Paetzel
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