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2005
Olefination
O 0284
03- 068
Efficient Aldehyde Olefination Reactions Catalyzed by an Iron Porphyrin Complex in an Ionic Liquid. — A commercial porphyrin complex is described as highly
(E)-selective catalyst for the olefination of various aldehydes with ethyl diazoacetate
in the presence of PPh3. The use of an ionic liquid as solvent component results in a
particularly easy, clean and selective reaction. — (SUN, W.; KUEHN*, F. E.;
Tetrahedron Lett. 45 (2004) 40, 7415-7418; Lehrstuhl Anorg. Chem., TU Muenchen,
D-85747 Garching, Germany; Eng.) — Mais
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