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2005
Polyphenylalkene derivatives
Q 0740
Sequential Assembly Strategy for Tetrasubstituted Olefin Synthesis Using Vinyl
Sulfide as a Platform. — A programmable and diversity-oriented,
03- 105 2-Pyrimidyl
regio- and stereoselective synthetic route for tetra- and triaryl substituted olefins is presented involving a site-selective and sequential assembly of aryl/heteroaryl substituents
onto a C=C core of sulfide (I). By changing the addition order of the aryl groups it is
possible to prepare all stereo- and regioisomers from a set of aryl groups. —
(ITAMI*, K.; MINENO, M.; MURAOKA, N.; YOSHIDA, J.-I.; J. Am. Chem. Soc.
126 (2004) 38, 11778-11779; Dep. Synth. Chem. Biol Chem., Grad. Sch. Eng., Kyoto
Univ., Nishikyo, Kyoto 615, Japan; Eng.) — Klein
2005
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