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2005
Iron
I 7100
04- 022
Multi-Iron Silicotungstates: Synthesis, Characterization, and Stability Studies of
Polyoxometalate Dimers. — As revealed by single crystal XRD compounds (III) and
(V) crystallize in the monoclinic space group C2/c with Z = 4. The structure of (III)
consists of two [α-SiFe3W9(OH)3O34]4- units linked by three Fe—µ-OH—Fe bonds and
that of compound (V) consists of two [α-Si(FeOH2)2FeW9(OH)3O34]4- Keggin units
linked by a single edge. — (ANDERSON, T. M.; NEIWERT, W. A.; HARDCASTLE,
K. I.; HILL*, C. L.; Inorg. Chem. 43 (2004) 23, 7353-7358; Dep. Chem., Emory
Univ., Atlanta, GA 30322, USA; Eng.) — W. Pewestorf
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