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2005
Enantioselective syntheses
O 0031
New Chiral Ligands Derived from Mandelic Acid: Synthesis and Application in
Asymmetric Phenyl Transfer Reaction to an Aromatic Aldehyde. — Mandelic
04- 027 the
acid-derived α-hydroxy-2-oxazolines (I) - (IV) are investigated as ligands in the asymmetric phenyl transfer reaction to aldehyde (V). Best results are obtained with ligands
(I) and (II). The configuration of the product is determined by the stereogenic center of
the oxazoline group. — (BOLM*, C.; ZANI, L.; RUDOLPH, J.; SCHIFFERS, I.;
Synthesis 2004, 13, 2173-2180; Inst. Org. Chem., RWTH Aachen, D-52074 Aachen,
Germany; Eng.) — Nuesgen
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