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2005
Carboxylic amides
P 0320
Nucleophilic Chain Substitution on Perfluoroketene Dithioacetals by Ethyl 2-TriAcetate. Application to the Synthesis of 2-Trifluoromethyl Succinic
04- 071 methylsilyl
Acid Derivatives. — Highly efficient substitution of the vinylic fluoride of perfluoroketene dithioacetals (I) using trimethylsilylacetate (II) is achieved that provides access to various 2-perfluoroalkyl succinic acid derivatives, particularly in the 2-trifluoromethyl succinimide series. — (BRULE, C.; BOUILLON, J.-P.; PORTELLA*, C.;
Tetrahedron 60 (2004) 44, 9849-9855; Lab. React. Sel. Appl., CNRS, Univ.
Reims-Champagne-Ardenne, F-51687 Reims, Fr.; Eng.) — C. Hettrich
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