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2005
Hydroxycarboxylic acids (ether carboxylic acids) and esters
Q 0450
Highly Diastereo- and Enantioselective Reactions of Enecarbamates with an
— By optimization of the copper catalyst and diimine ligand, optimized
04- 093 Aldehyde.
conditions are developed for the title reaction. For α-substituted enecarbamates the
reaction proceeds with excellent stereoselectivity, with anti-adducts derived from
(E)-enecarbamates and syn-adducts derived from (Z)-enecarbamates. —
(MATSUBARA, R.; VITAL, P.; NAKAMURA, Y.; KIYOHARA, H.; KOBAYASHI*,
S.; Tetrahedron 60 (2004) 43, 9769-9784; Grad. Sch. Pharm. Sci., Univ. Tokyo,
Bunkyo, Tokyo 113, Japan; Eng.) — Klein
2005
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