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2005
Hydrogenated naphthalene derivatives
Q 1010
A Novel Enantioselective Reaction. Palladium-Catalyzed Enantiodistinctive Reof Bicyclic Allylic Compounds. — The yield and enantiomeric excess of the
04- 104 action
products depends on the amount of malonate (II). The e.e. of (III) and (IV) is increased
if less than 1 equiv. (II) is used. However, the yield decreases dramatically. In addition,
(S)-(V) instead of (R)-(V) is formed. — (DAIMON, H.; OGAWA, R.; ITAGAKI, S.;
SHIMIZU*, I.; Chem. Lett. 33 (2004) 9, 1222-1223; Dep. Appl. Chem., Sch. Sci.
Eng., Waseda Univ., Shinjuku, Tokyo 169, Japan; Eng.) — C. Oppel
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