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2005
Structure
D 2000
05- 007
catena-Poly[[heptakis(dimethylformamide-?O)di-�oxo-tetra-�oxo-hexadeca�oxo-tetraoxolanthanum(III)octamolybdenum(IV)]-�-sodium(I)]. ? The structure of the title compound (IV) is determined by single crystal XRD (monoclinic, space
group P21/n, Z = 4). The structure consists of Na+ and DMF-coordinated La3+ cations
and infinite chains of ?-[Mo8O26] units. The La3+ ion is nine-fold coordinated to two
terminal O atoms of one ?-[Mo8O26] unit and to the O atoms of seven DMF molecules.
? (CHEN, S.-M.; LU*, C.-Z.; YU, Y.-Q.; ZHANG, Q.-Z.; HE, X.; Acta Crystallogr.,
Sect. C: Cryst. Struct. Commun. 60 (2004) 11, m549-m550; State Key Lab. Struct.
Chem., Fujian Inst. Res. Struct. Matter, Chin. Acad. Sci., Fujian, Fuzhou 350002, Peop.
Rep. China; Eng.) ? Schramke
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