close

Вход

Забыли?

вход по аккаунту

?

код для вставки
2005
Diastereoselective syntheses
O 0031
p-Menthane-3-carboxaldehyde: A Useful Chiral Auxiliary for the Synthesis of
Quaternary Carbons of High Enantiomeric Purity. — Several transforma05- 029 Chiral
tions are made with the products to demonstrate the versatility and efficiency of aldehyde (II) as a chiral auxiliary. They include the synthesis of α,α-dialkylated amino
acids and (+)-α-cuparenone, and a partial synthesis of the unnatural enantiomer of
(+)-cassiol. In most cases, the displacement reactions and rearrangements are efficient
in transferring the chirality. — (SPINO*, C.; GODBOUT, C.; BEAULIEU, C.;
HARTER, M.; MWENE-MBEJA, T. M.; BOISVERT, L.; J. Am. Chem. Soc. 126
(2004) 41, 13312-pp; Dep. Chim., Fac. Sci., Univ. Sherbrooke, Sherbrooke,
Que. J1K 2R1, Can.; Eng.) — Klein
Документ
Категория
Без категории
Просмотров
0
Размер файла
32 Кб
Теги
1/--страниц
Пожаловаться на содержимое документа