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2005
Sulfoxides
Q 0600
05- 083
Evidence for the Formation of an Iodosylbenzene(salen)iron Active Intermediate
in a (Salen)iron(III)-Catalyzed Asymmetric Sulfide Oxidation. — A new catalyst
system for the asymmetric oxidation of several aryl sulfides by PhIO is proposed based
on an asymmetric (salen)iron(III) complex. Since without iodosylbenzene only racemic
products are obtained it is shown that the intermediate iodosylbenzene(salen)iron(III)
complex is responsible for the formation of the specific active sites of oxidation. —
(BRYLIAKOV*, K. P.; TALSI, E. P.; Angew. Chem., Int. Ed. 43 (2004) 39,
5228-5230; Boreskov Inst. Catal., Sib. Branch Russ. Acad. Sci., Novosibirsk 630090,
Russia; Eng.) — S. Adam
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