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2005
Enantioselective syntheses
O 0031
Preparation and Resolution of a Modular Class of Axially Chiral QuinazoLigands and Their Application in Asymmetric Rhodium-Cata06- 037 line-Containing
lyzed Olefin Hydroboration. — A number of chiral title ligands is prepared. Their Rh
complexes is efficient catalysts for regio- and enantioselective hydroboration of various
vinylarenes. In some cases, for example starting from cis-stilbene and indene, excellent
regio- and enantioselectivity can be achieved. — (CONNOLLY, D. J.; LACEY, P. M.;
MCCARTHY, M.; SAUNDERS, C. P.; CARROLL, A.-M.; GODDARD, R.; GUIRY*,
P. J.; J. Org. Chem. 69 (2004) 20, 6572-6589; Dep. Chem., Univ. Coll., Belfield,
Dublin 4, Ire.; Eng.) — Jannicke
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