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2005
Amination
O 0268
06- 056
The Reaction of 2-Fluoroalkyl-1-iodoethylenes with Arylamines: A Facile Method
for the Synthesis of Fluoroalkylated Quinolines and Enaminoketones. — Intermediate enaminoaldehydes, derived from the title reaction as mixtures of (E)- and
(Z)-isomers, undergo further cyclization in the presence of strong acids to give 2-fluoroalkylquinolines or, by acidic hydrolysis, fluoroalkylated (Z)-enaminoketones. —
(ZHAO, F.; YANG, X.; LIU*, J.; Tetrahedron 60 (2004) 44, 9945-9951; Lab.
Organofluorine Chem., Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032,
Peop. Rep. China; Eng.) — Klein
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