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2005
Polyphenylalkane derivatives
Q 0720
Photochemical Polar Addition of 1,1-Diphenylethene Using Photosensitive Surin Stable Oil-in-Water Emulsion. — An aqueous NaOH solution of a photo06- 098 factant
sensitive surfactant (NDCA) is mixed with 1,1-diphenylethene (I) to form a stable
oil-in-water emulsion and excitation of the emulsion affords the alcohol (II) in good
yield. The photosensitive surfactant works more efficiently in heterogeneous system
(water) than in homogeneous system (organic solvent). — (YOSHIMI*, Y.;
HIGUCHI, M.; ITOU, T.; HATANAKA, M.; Chem. Lett. 33 (2004) 9, 1196-1197;
Dep. Appl. Chem. Biotechnol., Fac. Eng., Fukui Univ., Bunkyo, Fukui 910, Japan;
Eng.) — H. Haber
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