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2005
Other bioactive products
U 1300
Chemistry and Biology of Diazonamide A: Second Total Synthesis and Biological
— The second approach to diazonamide A involves a Robinson—Gab06- 217 Investigations.
riel cyclodehydration reaction using pyridine-buffered POCl3 to give the A-ring
oxazole. The scope and generality of this reaction is studied for several keto amides.
The method is also suitable for the synthesis of thiazoles and, in much less efficiency,
for furans. — (NICOLAOU*, K. C.; et al.; J. Am. Chem. Soc. 126 (2004) 40,
12897-12906; Dep. Chem., Scripps Res. Inst., San Diego, La Jolla, CA 92037, USA;
Eng.) — Klein
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