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2005
Cobalt
I 7200
07- 020
Novel Combination of Coordination Polyhedra in Mg2Co3Sn10+x — The First
Phase in the Mg/Co/Sn System. — Single crystals of the title compound, the first ternary compound in the Mg—Co—Sn system, are grown from the elements using excess
Sn as flux (evacuated silica tube, 850 °C, 1 h). The structure is determined on a crystal
of composition Mg2Co3Sn10.01 (hexagonal, space group P63/mmc, Z = 8). A small phase
width of 0 ≤ x ≤ 0.15 is observed due to the partial occupancy of one out of ten tin positions. — (SCHREYER, M.; KRAUS, G.; FAESSLER*, T. F.; Z. Anorg. Allg. Chem.
630 (2004) 13-14, 2520-2526; Lehrstuhl Anorg. Chem., TU Muenchen, D-85747
Garching, Germany; Eng.) — Schramke
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