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2005
Oxidation
O 0212
07- 043
Oxidation of Organic Compounds by Potassium Permanganate Supported on
Montmorillonite K10. — Efficient oxidation of primary benzylic and secondary alcohols to corresponding carbonyl compounds (II) (11 examples), sulfides to sulfones (IV)
(10 examples) and oxidative coupling of thiols to corresponding disulfides (VI) (9 examples) is achieved under both solution and solvent-free conditions using KMnO4 supported on montmorillonite. Surprisingly, reaction times under solvent-free conditions
are shorter or comparable to the reaction times in CH2Cl2. — (SHAABANI*, A.;
BAZGIR, A.; LEE, D. G.; Synth. Commun. 34 (2004) 19, 3595-3607; Dep. Chem.,
Shahid Beheshti Univ., Tehran, Iran; Eng.) — A. Forchert
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