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2005
Organo-silicon compounds
S 0060
Aluminum Chloride-Catalyzed Intramolecular Allyl-Migration Reaction of
and Trapping of the Intermediate with Allyltrimethyl07- 166 Allyl(chloromethyl)silanes
silane. — Reaction of allyl(chloromethyl)diorganylsilanes (I) with the Lewis acid
AlCl3 proceeds exclusively with allyl migration to afford homoallylchlorosilanes (II)
in moderate to good yields. Deallylation is the main side reaction affording products
(III), but no allylsilylation products are obtained. — (JUNG, H. Y.; PARK, Y.-A. W.;
YOO, B. R.; TAMAO, K.; JUNG*, I. N.; Organometallics 23 (2004) 21, 4910-4914;
Organosilicon Chem. Lab., Korea Inst. Sci. Technol., Seoul 130-650, S. Korea; Eng.)
— Mischke
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