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2005
Carbohydrates
U 0500
Synthesis and Chemistry of Noeuromycin and Isofagomine Analogues. —
variety of N-substituted analogues of the potent glycogen phosphorylase inhibitors
07- 194 A
isofagomine [cf. (IV), (VI)] and noeuromycin [cf. (XIV)] as well as 3-C-methyl analogue of noeuromycin (VII) are synthesized and evaluated for their inhibition of α- and
β-glucosidases. Moreover, the stability of noeuromycin (XV) is studied and it is found
to undergo Amadori rearrangement at neutral pH [→(XVI)]. — (LIU, H.;
LILLELUND, V. H.; ANDERSCH, J.; LIANG, X.; BOLS*, M.; J. Carbohydr. Chem.
23 (2004) 4, 223-238; Dep. Chem., Univ. Aarhus, DK-8000 Aarhus, Den.; Eng.) —
R. Staver
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