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2005
Catalysis
O 0020
08- 024
New Palladium Nanoclusters. Synthesis, Structure, and Catalytic Properties. —
The synthesis of new palladium nanoclusters, mainly particles with a nearly spherical
metal core and an average size of 18 Å is described. This new nanoclusters, derived
from palladium(II) carboxylates, catalyze hydrogenation of alkynes and alkenes, reduction of nitriles, oxidation of aliphatic and benzylic alcohols, oxidative esterification of
ethylene and propylene, and disproportionation of benzyl alcohol. The structure of the
new substances is elucidated based on NMR, X-ray photoelectron spectroscopy, and
EXAFS. — (STOLYAROV, I. P.; GAUGASH, Y. V.; KRYUKOVA, G. N.;
KOCHUBEI, D. I.; VARGAFTIK*, M. N.; MOISEEV, I. I.; Russ. Chem. Bull. 53
(2004) 6, 1194-1199; Kurnakov Inst. Gen. Inorg. Chem., Russ. Acad. Sci.,
Moscow 117907, Russia; Eng.) — H. Haber
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