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2005
Heterocyclic 3-membered rings
R 0050
Synthesis of Carboalkoxychloro- and Bromodiazirines. — A novel route to diazirlike (VII) and (VIII) is reported. Key step is the reductive dechlorination of
08- 102 ines
N,N,N-trichloroformamidines such as (VI) which are used for the first time as substrates in organic synthesis. Additionally, it is shown that thermolysis of the diazirines
in tetramethylethylene leads to cyclopropanecarboxylates. — (MARTINU, T.;
DAILEY*, W. P.; J. Org. Chem. 69 (2004) 21, 7359-7362; Dep. Chem., Univ. Pa.,
Philadelphia, PA 19104, USA; Eng.) — Jannicke
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