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2005
Organo-silicon compounds
S 0060
Protecting Group Effects on the Efficiency of the Ruthenium-Catalyzed
Reaction. — Electron deficient substituents on alkene (II) lead to the
08- 181 Alder-Ene
desired products (III), in excellent yields and selectivity. Only one isomer is obtained.
Electron-rich protecting groups or substituents are found to be poor substrates. The
length of the carbon chain in (II) is also important. — (HARTLEY, J. P.; PYNE, S. G.;
Synlett 2004, 12, 2209-2211; Dep. Chem., Univ. Wollongong, Wollongong,
N. S. W. 2522, Australia; Eng.) — C. Oppel
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