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2005
Carbohydrates
U 0500
Stereospecific Uncatalyzed α-O-Glycosylation and α-C-Glycosidation by Means
a New D-Gulal-Derived α Vinyl Oxirane. — The title method offers a simple and
08- 210 of
efficient approach to α-O- and α-C-glycosides such as (IV) and (VIII). Highly stereoselective formation of disaccharides is also possible. To achieve stereospecific
α-O-glycosidation it is necessary to perform the reaction with a limited amount of
alcohol. — (DI BUSSOLO, V.; CASELLI, M.; ROMANO, M. R.; PINESCHI, M.;
CROTTI*, P.; J. Org. Chem. 69 (2004) 21, 7383-7386; Dip. Chim. Bioorg. Biofarm.,
Univ. Pisa, I-56126 Pisa, Italy; Eng.) — Jannicke
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