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2005
Alcohols
Q 0230
09- 062
Chemoenzymatic Synthesis of Enantiomerically Pure 1,2-Diols Employing Immobilized Lipase in the Ionic Liquid [bmim]PF6. — The conversion of α-halo ketones
(I) to α-acetoxy ketones (III) is efficiently promoted by [bmim]Br as the reaction solvent. The enzymatic kinetic resolution of racemic diols (IV) promoted by [bmim]PF6
as the reaction solvent leads to significantly enhanced enantioselectivity. —
(KAMAL*, A.; CHOUHAN, G.; Tetrahedron Lett. 45 (2004) 48, 8801-8805;
Biotransform. Lab., Indian Inst. Chem. Technol., Hyderabad 500 007, India; Eng.) —
Mais
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