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2005
Cycloalkylphenyl derivatives
Q 0760
Synthesis of Nitrogen-Functionalized Cyclohexanes Using Chemoselective ConjuAddition of Phenyllithium to Linear ω-Nitro-α,β,ψ,ω-Unsaturated Ester and
09- 086 gate
Subsequent Stereoselective Intramolecular Nitro-Michael Cyclization. — The
synthesis of the starting material (I) is also described. The stereochemistry of
(IV)—(VI), which may be used for the total synthesis of lycoranes, is determined by
further chemical modifications. — (YASUHARA, T.; NISHIMURA, K.; OSAFUNE,
E.; MURAOKA, O.; TOMIOKA*, K.; Chem. Pharm. Bull. 52 (2004) 9, 1109-1113;
Grad. Sch. Pharm. Sci., Kyoto Univ., Sakyo, Kyoto 606, Japan; Eng.) —
K. Schneider
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