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2005
Thiazole derivatives
R 0260
Thiazolidin-4-one Formation. Mechanistic and Synthetic Aspects of the Reaction
Imines and Mercaptoacetic Acid under Microwave and Conventional Heating.
09- 113 of
— Microwave heating provides a superior protocol for preparation of title compounds
(III) from condensation of benzylidene anilines with mercaptoacetic acid. Based on
NMR studies two different reaction mechanisms, acting in benzene and in DMF respectively, are proposed. The investigation is presented in continuation of synthetic studies
on potentially bioactive thiazolidinones. — (BOLOGNESE*, A.; CORREALE, G.;
MANFRA, M.; LAVECCHIA, A.; NOVELLINO, E.; BARONE, V.; Org. Biomol.
Chem. 2 (2004) 19, 2809-2813; Dip. Chim. Org. Biochim., Univ. Studi "Federico II",
I-80126 Napoli, Italy; Eng.) — Nuesgen
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