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2005
Epoxidation
O 0218
10- 035
Catalytic Action of Cobalt and Nickel Complexes of Porphyrins and Their Polymer-Bound Derivatives in Epoxidation Reaction of Styrene. — Crosslinked polystyrene-bound porphyrins (I) as well as the free porphyrins (I) are tested as catalysts in
the epoxidation of styrene with oxygen in the presence of isobutyraldehyde as reductant. Polymer-bound cobalt complex (Ia) exhibits the highest selectivity for the formation of phenyl oxirane. — (NIKOLAEVA, O. I.; KUREK, S. S.; AGEEVA, T. A.;
KOIFMAN, O. I.; Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 47 (2004) 2,
146-149; Ivanovskii gos. khim.-tekhnol. univ., Ivanova, Russia; Russ., Abstr. Eng.)
— Klein
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